Methanol (1) +
water (2) binary
i)
VLE
type: non-azeotropic mixture
ii)
Vapor
pressures:
p1s=80.9*exp(para1*tclap**3+para2*tclap**2+para3*tclap)
[bar]
para1=0.212768828771579
para2=-0.319352375891615
para3=8.23174708919747
tclap=1-1/(T/512.6)
T: temperature [K]
p2s=221.2*exp(para1*tclap**3+para2*tclap**2+para3*tclap)
[bar]
para1=0.222438359031832
para2=-0.0522401918107863
para3=7.17725676105391
tclap=1-1/(T/647.3)
T: temperature [K]
iii)
y1,center =aT**2+bT+c (-10 deg C < T < 121 deg C)
a=1.4239528
b=-0.00137058
c=0.884655
T: temperature
[deg C]
The
values, T and y1,center, denote temperature and y1 value at x1=0.5,
where x1 is the composition of component 1 in the liquid phase and y1 is the
composition of component 1 in the vapor phase.
Fig. 3
y1,center
vs T for the methanol (1) + water (2) binary, (○) y1,center
determined from constant temperature VLE data, (●) y1,center
determined from constant pressure data, and (−)
predicted using the PPM.